Mon 23 Feb 2009
Bismuth oxychloride – friend or foe?
Posted by MollyLoretta under Beauty Blog
[9] Comments
I know people who have no issues with this ingredient which is used by many major mineral cosmetic companies — some people wear it and love it to death, while others (including myself) get an itching, burning rash, and sometimes even bleeding or cystic acne.
The issue that is in mineral cosmetics that can cause such a problem is called bismuth oxychloride. Bismuth oxychloride is made of three separate elements. The first is bismuth, which rests nicely on the periodic table inbetween arsenic and atimony; it’s number 83 and has the obvious abbreviation of Bi (if you wanted to go look it up). Once bismuth is harvested, it then goes through several refining processes to remove extra dangerous elements -such as lead- and is then chlorinated, giving us bismuth chloride. This chemical compound smells like hydrochloric acid. After this process, the bismuth chloride is mixed with water, replacing some of the chloride atoms with oxygen from the water. The result? Bismuth oxychloride. (Bismuth oxychloride is not a natural occurring element, which makes it silly to call it organic when in reality, the process it takes to get to its end result is far from natural.)
Bismuth oxychloride comes in two forms, crystalline and pearl. Crystalline bismuth oxychloride will give you that “natural glow” appearance in your mineral cosmetics, and the pearl will give you a more matte finish. Obviously, most companies tend to use the crystalline form just because they really do want to give you that natural glow.
The problem with crystalline bismuth oxychloride is that it can cause severe irritation. When you buff it into the skin, you are buffing these teeny little crystals into your pores, which scratches delicately at your skin, and causes cystic acne. Not to mention, an increasing number of women are allergic to it — upwards of 75% of users will develop an allergy before three years of use, while the argument of Bare Minerals is that women have allergies and reactions to preservatives in cosmetics (which are called unnatural, whilst one of their ingredients is also unnatural), less than 5% of women in studies show any reaction to preservatives (sad, yes?). And to think, all preservatives do is keep our cosmetics from having an experation date.
We must also remember that our bodies try to purge and reject anything that’s bad from it. If we ingested arsenic, our bodies would go through a series of painful processes in attempt to rid itself of the toxin (though, we would most likely die in the process). Since the skin is the body’s largest organ, it’s safe to assume that it would do the same with ingredients such as bismuth oxychloride.
It is a common ingredient in many products for the face, eyes, lips and nails. It is an extremely inexpensive filler, making it great for companies who don’t want to spend more money on more expensive minerals.
I had to quit my job at Ulta because of bismuth oxychloride — after a shift at work as a prestige cosmetics consultant, my hands would either be red, irritated and itching; or literally bleeding. My future sister-in-law had unbelievable cystic acne caused by the ingredient, and that’s coming from a board certified dermatologist who spent three months with her undoing the damage the product caused. Another girl I went to school with within two weeks of using, it was making her sensitive skin bleed.
If you love mineral make up, my suggestion is to check your ingredient listing. Bismuth oxychloride can also be used for pigmentation, but there are plenty of cosmetics companies that either do not include it, or in the ingredients -down at the very bottom- it says “may include” followed by bismuth oxychloride — these products would be your best, and safest bet.
SOURCES:
1. http://potency.berkeley.edu/chempages/BISMUTH%20OXYCHLORIDE.html
2. http://ezinearticles.com/?Bismuth-Oxychloride-in-Mineral-Makeup&id=1514493
3. http://community.qvc.com/topic/Beauty-Dilemmas/Worried-Bismuth-Oxychloride/4000042048
4. http://reviews.ebay.com/Watch-out-for-Bismuth-Oxychloride_W0QQugidZ10000000001831889?ssPageName=BUYGD:CAT:-1:LISTINGS:1
5. http://www.makeuptalk.com/forums/f148/mineral-makeup-bismuth-oxychloride-56080.html
6. http://www.webmd.com/skin-beauty/features/the-lowdown-on-mineral-makeup
7. http://www.carefreebeauty.eu/sensitiveskin/bismuth
8. http://www.isnare.com/?aid=345426&ca=Womens+Interest
Mineral foundations that do not (or most likely do not except in certain colors and in very small, non-irritating doses) include bismuth oxychloride:
1. Everyday Minerals
2. Nixie Matte Loose Mineral Foundation
3. Jane Iredale
4. Mary Kay
5. Beauty From The Earth
6. MAC Cosmetics (I spent nearly 20 minutes on the phone waiting for the rep to figure this one out for you guys
I was so happy to see that they don’t!)
7. Afterglow Cosmetics
Do you know of any other mineral cosmetics that do not contain the skin irritant bismuth oxychloride? Please e-mail them to me at molly.loretta@gmail.com!

9 Responses to “ Bismuth oxychloride – friend or foe? ”
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Hi Molly,
Thanks for spreading the word about the potential problem with this ingredient. It has wreaked havoc for many women to be sure.
However, I did want to correct one product you have listed as bismuth oxychloride free or low dose….Raw Minerals first ingredient is Bismuth Oxychloride in their Active Mineral Foundaton..so First ingredient makes up the majority of this product and this would be a point of concern for women who may be considering this product for personal use and may take this recommendation at face value without actually checking the label.
Here is a link for this product
http://www.rawnaturalbeauty.com/index.cfm?action=shop.viewproduct&product_category_id=19&product_id=313
Thanks again
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MollyLoretta Reply:
November 20th, 2009 at 10:14 am
Thank you for bringing this to my attention. When I added it it was being promoted as a bismuth free product. I’ll definitely have to edit this and remove it from the list!
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Thanks so much for writing this and spreading the word about bismuth oxychloride. I recently switched from Youngblood due to the bismuth oxychloride irritating my skin! I have now found a new makeup brand that is free from bismuth oxychloride and my skin has never been better. This makeup brand is pinQ.me Mineral Makeup and their website is http://www.pinq.me
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i also wanted to comment on the bismuth oxy ingredient in mineral makeup. i keep hearing so much talk about mineral makeup and decided to stop at the counter to find out what is so great about it.
i went to the prescriptives counter at macy’s a yr. ago and i loved the way the makeup looked immediately. so i purchased it that day.
within 3 weeks i noticed that my skin was irrated and started getting these huge pimples. keep in mind that im not someone who has acne problems so i figured it was the makeup. did my own research and yep, it was the bismuth ingredient that caused me to have those huge breakouts.
it’s unforutnate though b/c that makeup looked great on my skin, just not at the cost of my skin breaking out.
after i returned it to prescriptives and stopped using it, my skin cleared up within a few weeks.
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Unfortunately, MAC appears to have bismuth oxychloride in its ingredient list (eye shadow) based on findings on other web sites. With so many people allergic to this ingredient, companies really need to start using an alternative.
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I’m still looking for my ideal inexpensive mineral foundation. The first mineral brand I tried was Bare Escentuals, really loved how it looked, but got the itch when the weather was hot. Since then I’ve avoided brands that use bismuth. Brands like LilyLolo and Earthnicity have been fine, no itching at all. However I was surprised that when I tried Barefaced Beauty, which claims not to contain bismuth, the itching was 10 times worse than what I experienced with Bare Escentuals. I compared their ingredients to those of Lily Lolo and Earthnicity and found they were identical! Clearly Barefaced isn’t being completely honest. Other Brands that I’ve yet to try (in the UK) that claim to be bismuth free are: Rockface minerals, Firstlight cosmetics, Orissa, Erth minerals.
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Marc Reply:
August 16th, 2010 at 3:12 pm
Well said! Thank you for informing people about bismuth oxychloride.
Just one remark: The issue with preservatives (like parabens) is not about allergic reactions but carcinogenic potential. I do not understend why companies still formulate with this materials. there are plenty of safe or more tested alternative… Cutting costs, I guess.
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MollyLoretta Reply:
August 22nd, 2010 at 1:44 pm
There is no evidence showing that they are potentially carcinogenic.
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